Scotch whisky
From Memory Alpha, the free Star Trek reference.
Scotch whisky is an Earth alcoholic beverage, a whisky originating from Scotland.
Captain Montgomery Scott had a refined taste for Scotch. Chekov once claimed that Scotch "was inwented [sic] by a little old lady from Leningrad" when Scotty attested to Scotch's superiority over vodka. Scotty's palate was sensitive enough to tell the synthehol variety from the real thing. (TOS: "The Trouble with Tribbles"; TNG: "Relics")
Scott also used a bottle of Scotch to intoxicate one of the Kelvans who took control of the USS Enterprise in 2268. (TOS: "By Any Other Name")
After the incident at Nimbus III, Scott offered Klingon General Korrd some Scotch with the words "I never thought I'd be drinking with a Klingon." (Star Trek V: The Final Frontier)
McNary offered to stop by Dixon Hill's office with a bottle of Scotch. (TNG: "The Big Goodbye")
Dixon Hill ordered himself a neat Scotch at Rex's Bar. According to Rex, it was Hill's usual beverage. (TNG: "Manhunt")
Julian Bashir and Miles O'Brien drank Scotch and sang Jerusalem in 2371. (DS9: "Explorers")
Scotch was a favorite of Julian Bashir after leaving the Battle of Britain holoprogram. He liked it neat. (DS9: "Homefront")
Benjamin Sisko served Scotch at a dinner he had organized for his senior staff in late 2373. (DS9: "In the Cards")
In 2374, Worf and Miles O'Brien wagered a bottle of bloodwine against a bottle of Scotch whiskey if Jadzia Dax beat Quark in a game of tongo. Quark was triumphant and O'Brien told Worf that he would like "Single malt. Preferably something from the Highlands". (DS9: "Change of Heart")
Sisko drank Scotch when he was recording a personal log on his role in bringing the Romulans into the Dominion War. (DS9: "In the Pale Moonlight")
Several weeks later, Scotch was served at Lisa Cusak's wake. (DS9: "The Sound of Her Voice")
Miles O'Brien replicated a chewing gum, called Wee Bairnes, in the flavor of Scotch, and gave a piece to Julian Bashir. (DS9: "Take Me Out to the Holosuite")
Scotch was also available in Vic's Las Vegas Lounge. Vic Fontaine himself enjoyed it. (DS9: "It's Only a Paper Moon")
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